Duncan James leaves Alyssa Barmonde behind when he is seen with another girlfriend from Married At First Sight

After a rocky few weeks between Married At First Sight couple Duncan James and Alyssa Barmonde, it looks like the handsome groom has officially called it quits with his TV wife.

The pairing was one of the strongest pairings at the start of this MAFS season, but cracks have started to emerge.

And despite Duncan’s efforts to understand Alyssa’s needs, it seems like she’s really moved on with a ‘villain’ from the show’s previous season.

The 36-year-old was spotted getting cozy with Carolina Santos during a wild night out in Sydney in January, two months after filming for this season wrapped.

In photos obtained by yahoo lifestyleDuncan and Carolina shared an intimate conversation while whispering in each other’s ears.

Duncan James (left) has officially broken up with his TV wife. The 36-year-old was spotted getting cozy with Carolina Santos during a night out in Sydney in January, two months after filming for this season wrapped.

A snapshot showed Carolina hugging Duncan, who has been dubbed this season’s “good guy.”

Carolina, who was ‘married’ to Dion Giannarelli before moving on with her co-star Daniel Holmes in their season, seemed to be having a great time with Duncan.

“It looked like they were on a date, but they had other friends with them,” a source told Yahoo Lifestyle.

Carolina, who was ‘married’ to Dion Giannarelli before moving on with her co-star Daniel Holmes in their season, seemed to be having a great time with Duncan.

It’s not the first time Duncan has been seen with a girlfriend partner since filming wrapped – he attended Evelyn Ellis’s Sydney viewing party last month.

Footage from the evening, taken by Daily Mail Australia, showed Evelyn drinking a bottle of tequila and pouring champagne into Duncan and Hugo’s mouths.

Fans have since rallied behind Duncan after he got into an argument with his wife Alyssa when they reunited after the swingers challenge during Monday’s episode.

Alyssa continued their disagreements from Sunday’s commitment ceremony, telling Duncan that she would “never understand” the pressures of being a single mother.

It’s not the first time Duncan has been seen with a girlfriend partner since filming wrapped, he attended Evelyn Ellis’s Sydney viewing party last month.

Footage from the evening, taken by Daily Mail Australia, shows Evelyn drinking a bottle of tequila and pouring champagne into Duncan’s mouth.

Duncan asked her to help him try to understand.

I don’t think I can agree to that. Full stop,’ she replied.

Alyssa then left the couple’s apartment with her suitcase, arguing that she needed time to herself.

The ordeal left Duncan breaking down in tears on camera.

Since then, fans have rallied behind Duncan after he got into an argument with his wife Alyssa when they reunited after the swingers challenge during Monday’s episode. Alyssa left the couple’s apartment, arguing that she needed time to herself. The ordeal left Duncan bursting into tears on camera.

“I feel like I’m trying to be positive, trying to reassure, but there seems to be a lot of prayers from Alyssa about why this won’t work,” she explained.

‘He was combative. She wants to go now. I feel like I’m shooting in the dark sometimes.’

“I feel more rejected in this relationship than in any relationship I’ve ever been in,” he added.